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What determines the skies colours at sunset and sunrise?

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From blue to red to orange and yellow. What are the determining factors for our eyes to see certain colours in the sky?

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What?! allow it What what What? what? complete regulate resolve rule actuate arbitrate cinch clinch dispose drive end figure finish halt impel incline induce move opt ordain persuade predispose settle tap terminate call the shots fix upon nail down pin down take a decision ultimate wind up wrap up bear begin commence create discourage dissuade hinder initiate prevent repress start stop suppress doubt hesitate miss overlook waver detect verify learn tell see ascertain demonstrate work out establish check unearth tumble certify hear divine add up to make out figure out boil down to catch on have a hunch size up confuse invalidate disprove elect fix doom fate predestine preordain predetermine purpose destine foreordain finger preform make up mind unsettle destroy ignore control impose influence shape limit decide measure affect plot delimit lead devise manage modify direct bound command invent circumscribe condition mark off mismanage follow neglect let go affecting breathtaking climactic comic dramaturgic dramaturgical effective electrifying emotional expressive farcical histrionic impressive melodramatic powerful sensational spectacular startling striking sudden suspenseful tense histrionical the The allow it azure empyrean firmament heavens lid vault welkin celestial sphere the blue upper atmosphere vault of heaven wild blue yonder earth Sky allow it sky dusk nightfall sundown twilight eve evening eventide gloaming close of day crepusular light daybreak sunrise dark dimday dimmet gloom night sunset dawn light day brightness duskiness blackness darkness dimness murkiness lightness black close decline dim early black even late afternoon morning crepuscule vespers Sunset allow it sunsets along with also as a consequence as well as furthermore including moreover together with additionally and plus again along as well besides conjointly further in conjunction with in like manner likewise more more than that on top of over and above still to boot too withal added aggrandized amassed another augmented bounteous deeper else enhanced exceeding expanded extended extra farther fresh heavier higher in addition increased innumerable larger major massed new numerous other spare supplementary too many wider fewer less allow it And? And's aurora cockcrow dawn dawning daybreak daylight light morn morning sunup break of day bright early bright darkness evening eventide night sundown sunset brightening crack of dawn first blush first brightening peep of day prime prime of the morning sunrise cockcrowing first light day peep wee hours finish conclusion end ending setting dusk dayspring day daytime during the day light of day sunlight sunshine
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